Thermal expansion of nepheline-kalsilite crystalline solutions

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Thermal expansion of nepheline-kalsilite crystalline solutions

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dc.contributor.author Hovis, Guy L.
dc.contributor.author Crelling, J.
dc.contributor.author Wattles, D.
dc.contributor.author Dreibelbis, B.
dc.contributor.author Dennison, A.
dc.contributor.author Keohane, M.
dc.contributor.author Brennan, S.
dc.date.accessioned 2009-04-07T13:19:12Z
dc.date.available 2009-04-07T13:19:12Z
dc.date.issued 2003-06
dc.identifier.citation Hovis G. L., et al. (2003) "Thermal expansion of nepheline-kalsilite crystalline solutions." Mineralogical Magazine 67 (3): 535–546. en_US
dc.identifier.uri http://hdl.handle.net/10385/485
dc.description.abstract Eleven nepheline–kalsilite crystalline solutions with various proportions of K:Na have been studied from room temperature to 1050/1150ºC by X-ray powder diffraction. Nepheline expansion is relatively high and little affected by composition, whereas kalsilite expansion is lower but affected to a significant degree by K:Na ratio. The generally higher rate of expansion in nepheline is apparently related to the collapse of the tetrahedral framework around the smaller of its two alkali sites. Occupancy of these sites by the relatively small Na ion further extends the potential for thermal vibration before the structure is stretched to the critical degree required for phase transformation. Once the structure changes to that of kalsilite, with its single alkali site, an increase in content of the larger K ion limits the degree to which kalsilite can expand. Crucial to the overall expansion behaviour of these minerals are the specific tetrahedral configurations of nepheline vs. kalsilite, the number and geometry of their alkali sites, the occupancies of those sites, and the flexibility inherent in each structure that allows for adjustment with increasing temperature. en_US
dc.language.iso en_US en_US
dc.publisher Mineralogical Magazine en_US
dc.title Thermal expansion of nepheline-kalsilite crystalline solutions en_US
dc.type Article en_US
dc.identifier.doi 10.1180/0026461036730115

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